
Reactions of Xenon with Iridiumand Osmiumhexafluoride
Abstract
Xenon and Iridiumhexafluoride react at temperatures above room temperature forming XeF+IrF6–. In presence of SbF5 FXe+IrSbF11– is formed. Xenon and Osmiumhexafluoride form in solution a blue charge transfer complex that cannot be isolated as a solid.
Keywords
Xenon oxidation, iridium hexafluoride, osmium hexafluoride, fluoro xenon hexafluoroiridate crystal structure
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Copyright (c) 2013 Farhad Tamadon, Stefan Seidel, Konrad Seppelt

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