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Reactions of Xenon with Iridiumand Osmiumhexafluoride

Farhad Tamadon, Stefan Seidel, Konrad Seppelt

Abstract


Xenon and Iridiumhexafluoride react at temperatures above room temperature forming XeF+IrF6–. In presence of SbF5 FXe+IrSbF11– is formed. Xenon and Osmiumhexafluoride form in solution a blue charge transfer complex that cannot be isolated as a solid.

 


Keywords


Xenon oxidation, iridium hexafluoride, osmium hexafluoride, fluoro xenon hexafluoroiridate crystal structure

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