Cover Image

Synthesis, Crystal Structures and Catalytic Oxidation of Manganese(III) Complexes Derived from Salen-Type Schiff Base N,N’-Bis(5-nitrosalicylidene)ethane-1,2-diamine

Qing-Bin Li, Yong-Jun Han, Gan-Qing Zhao, Ling-Wei Xue

Abstract


Two mononuclear Schiff base manganese(III) complexes, [MnL(N3)(OH2)]·CH3OH (1) and [MnL(NCS)(OH2)]·H2O (2), where L is the dianionic form of N,N’-bis(5-nitrosalicylidene)ethane-1,2-diamine, have been prepared and characterized by elemental analysis, IR and UV-Vis spectroscopy and single crystal X-ray diffraction. The Mn atom in each complex is in an octahedral coordination. Molecules of the complexes are linked through intermolecular hydrogen bonds. Catalytic properties for epoxidation of styrene by the complexes using PhIO and NaOCl as oxidant have been studied.

 


Keywords


Synthesis; Crystal structure; Schiff base; Manganese complex; Catalytic oxidation

Full Text:

PDF


DOI: http://dx.doi.org/10.17344/acsi.2017.3416

Refbacks

  • There are currently no refbacks.


Copyright (c) 2017 Qing-Bin Li, Yong-Jun Han, Gan-Qing Zhao, Ling-Wei Xue

Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 International License.