Polypropylene Blends with m-EPR Copolymers: Mechanical and Rheological Properties

The effects of two metallocene ethylene-propylene-based elastomers (m-EPR1 and m-EPR2) differing in molecular mass and viscosity on mechanical, rheological and interfacial properties were compared. The m-EPR elastomers were added to iPP in 2.5, 5, 10, 15, and 20 vol.%. Torque values, elongation at break and impact strength measured of the iPP/m-EPR1 blends were higher than the iPP/m-EPR2 blends due to higher molten viscosity of m-EPR1 than m-EPR2 copolymer. Slight differences in Young moduli as well as in tensile strength at yield and at break might indicate that tensile properties of iPP/m-EPR blends were not significantly affected by difference in viscosity or molecular mass, miscibility and spherulite size. Optimization diagrams indicated the metallocene m-EPR copolymers are efficient impact modifiers for polypropylene and showed good balancing of mechanical properties in iPP/m-EPR blends.

The investigation of polypropylene-based copolymers or ethylene-propylene elastomers with polyolefins, was mostly oriented on achieving better optimization of mechanical properties and consequently other properties as well.
Zhang and coworkers studied the influence of copolymerization on structure and mechanical properties of iPP/EPR random copolymer in situ blends.The investigation showed that the mechanical properties of the blends, including the impact strength and flexural modulus, depended on copolymerization conditions.The impact strength was influenced also by the amount of random copolymer. 12itta et al. investigated the mechanical properties for the binary blends of isotactic polypropylene (iPP) and random copolymers of ethylene-propylene (EP). 13The iPP/ EP blends were partly miscible in the melt.The addition of the novel EP copolymers played an important role in the modification of mechanical properties of iPP and final morphology. 13Grain et al. studied the influence of the molecular weight of dispersed phase in ethylene-propylene rubber in modified isotactic polypropylene (iPP/EPR) blend. 14The ductile-brittle transitions did not correlate linearly with M w , suggesting the macroscopic behavior of the blend is controlled by the morphology of the EPR particles.Dynamical mechanical analysis (DMA) showed relationship between molecule relaxation processes and mechanical properties.Similar investigation was done by Oracio and coworkes 15 who studied the rubber molecular relaxations with DMA and obtained information about mechanical characteristics and the deformation mechamisms for the investigated iPP/EPR materials. 15Oracio and coworkes showed that the iPP phase is more effective in stiffening the matrix and provide better tensile elastic behaviour than EPR based materials. 15n iPP/EPR blend in-situ synthesized by spherical Ziegler-Natta catalyst has also been investigated by the same investigation group. 16The synergistic effect between random copolymer and copolymer has been found to be the key factor for high impact strength at low temperature.The thermal study clearly shows that, polyethylene PE segments of different lengths in the segmented copolymer fractions can form crystalline lamellae of different thickness. 16he influence of the nucleation (agents) of ethylenepropylene rubber modified isotactic polypropylene on ductile-brittle transition of iPP/EPR blends was studies by Grein and coworker and have found positive effects on mechanical properties. 17rongtorsak and coworkers also reported improvement of mechanical properties of iPP/m-EPR blends with the addition of calcium stearate as β-nucleation agent, especially the improvement of notched Izod and strength. 18hereby, metallocene EPR copolymers (m-EPR) with propylene being the major component (> 80 wt% according to producer) were applied as impact modifiers for polypropylene in our investigation.Two chosen Vista-maxx thermoplastic elastomers, signed as m-EPR1 and m-EPR2, are actually specialty co/terpolymers of propylene balanced with ethylene and other α-olefins with different viscosity (e.g.different molecular mass) and compatible with various polyolefins in different extent. 19,20he goal was to study the mechanical properties of iPP/m-EPR blends and to compare the experimental and calculated results using some custom models for mechanical properties.Comprehensive study of interaction in iP-P/m-EPR blends with different content of elastomer was also preformed to estimate the influence of interactivity and possible miscibility of m-EPR elastomers with isotactic polypropylene primarly on mechanical properties.

1. Materials
Isotactic polypropylene (trade name Moplen) used as polymer matrix was supplied by LyondellBasell, Netherlands.Two metallocene propylene-ethylene copolymers with different viscosity are used from Exxon Mobil producer. 19,20The properties of used polymers and fillers are listed in Table 1.

Sample Preparation
Binary iPP/m-EPR blends were prepared in a Brabender Plasti-Corder kneading chamber.The content of m-EPR copolymers in blends was 2.5, 5, 10, 15 and 20 vol.%.The components were kneaded for 7 min, in a chamber preheated to 200 °C, with a rotor speed of 50 min -1 .After kneading, the melt was rapidly transferred to a preheated laboratory press and compression moulded into 1-and 4-mm thick plates.The pressing temperature was 220 °C, the pressure 100 bar and the pressing time 14 min for 1-mm, and 11.5 min for 4-mm thick plates.The plates were used for specimen preparation for morphology observation and mechanical testing.

3. 1. Steady State Torque (τ M )
The torque value (τ M ) of iPP/m-EPR blends was determined from the diagram of kneading in the Brabender kneading chamber.The average τ M value was calculated on the basis of 5 measurements carried out for each sample with the same filling volume.

3. Tensile Tests
Tensile properties of iPP/m-EPR blends (Young's modulus, yield stress and strain, tensile strength at break, elongation at break) were measured according to ISO 527 standard using Zwick 147,670 Z100/SN5A apparatus at 23 °C and strain rate of 2 mm/min.For each sample, 5 measurements were carried out.

3. 3. Notched Impact Strength
Notched impact strength of iPP/m-EPR blends was measured by Zwick apparatus at 25 °C according to Charpy test (DIN 53453).For each sample, 12 measurements were carried out.

3. 4. Contact Angle Measurement
Surface free energies of used polymers, as well as their corresponding dispersive and polar components, were determined by measuring contact angle.Contact angles of the isotactic polypropylene and propylene-ethylene copolymers were measured on a contact angle goniometer DataPhysics OCA 20 Instrument at temperature of 23 °C.Sessile drops (2µL) of test liquids: water (distilled twice λ = 1.33 µLcm -1 ), formamide (p.a.99.5%, Fluka) and diiodomethane (p.a.99%, Aldrich) were used for the advancing contact angle measurements at 23 °C.The surface tensions of the test liquids used for contact angle measurements are presented in Table 2.The average values of at least five drops at different places of the same sample were taken and the standard deviation was always less than 2%.
Surface free energies of the iPP and elastomers (γ l ) were calculated using harmonic mean equation according to Wu's model presented with equation (1): 21 (1) where γ p was the dispersive and γ d the polar component of the surface free energy (surface tension), γ l and γ s were the surface tension of liquid and surface free energy of solid, respectively.
Surface free energies of the iPP and elastomers were presented in Table 4.The interfacial free energy, γ AB , work of adhesion, W AB , and spreading coefficient, S AB , of all polymer/elastomer blend pairs were calculated from obtained γ values using equations (2-4) and presented in Table 5: (2) where subscripts A and B correspond to the phases in blends (A-matrix, B-elastomer) and superscripts d and p mean dispersed and polar components of interfacial free energy γ.The results from Table 4 and Table 5 are presented in Adhesion parameters of iPP/m-EPR blends section.

1. The Mixing Torque Values of the iPP/m-EPR Blends
The mixing torque values (τ M ) provide information how toughening elastomeric m-EPR modifier affect processabillity of the iPP/m-EPR blends.The torque values can be considered as a measure of the viscosity under the same mixing conditions, including the same filling volume.The torque τ M increases by adding components in batch mixer and decreases after the polypropylene melting and reaches constant value around sixth minute of mixing (τ M values in Figure 1 are measured at 7 th min) due to process of homogenization and equalized viscosity of blends. 22he τ M values of two blend systems begun to diverge already at minimal addition of m-EPR's (2.5 vol.% showed in Figure 1): the blends with m-EPR1 exhibit the trends of somewhat higher τ M values then with m-EPR2 (especially at 20 vol.% of added m-EPR's) due to significantly higher viscosity of m-EPR1 than m-EPR2 copolymer (see MFI values in Table 1).Moreover, the τ M values of blends with m-EPR1 (MFI = 4.5 g 10 -1 min -1 ) were somewhat higher than plain polypropylene (MFI = 6.0 g 10 -1 min -1 ) due to somewhat higher viscosity of m-EPR1 than plain iPP.

2. 1. Young's Modulus
]23 An almost linear decrease of close E values is in accordance with the parallel model with linear combination of plastic and elastomeric components. 24Although m-EPR2 elastomer has significantly lower viscosity than m-EPR1 (MFI = 20 g 10 -1 min -1 in comparison to 4.5 g 10 -1 min -1 for m-EPR1) due to lower molecular mass (M n = 48.100 in comparison to 92.900 g mol -1 for m-EPR1) the blends with m-EPR2 exhibit just minor decline of the E values than blends with m-EPR1 elastomer.
For a further analysis of the E data, the experimental values were compared with the values calculated by the different theoretical models based on the modulus-concentra-tion dependence of two-phase polymeric materials.The elastic moduli of stiffness of a material is affected by the elastic moduli of all components, fraction of components, the morphology and the interactions between the components.The E models usually presume the idealization about perfect adhesion between the phases, spherical particles and perfectly distributed minor phase through the matrix. 25,26The most simple of all models for predicting the moduli of a composite or a blend is known as the parallel model and has been considered as the upper limit of elastic modulus: (5)   where the E 1,2 is the elastic modulus of compound, E 1 and E 2 are the elastic modulus of components.The series model represents the lower limit of elastic modulus: (6)   Takayanagi developed a combined series-parallel model for the tensile property E, by introducing a degree of parallelinity into the series model. 27,28It was assumed that the two-phase material can be treated as a combination of series and parallel elements.The equation for Takayanagi parallel model is given as: (7)   and for series model: (8)   where the E 1 is the property of the matrix phase; E 2 is the property of the dispersed phase.Quantities λ and φ are geometry factors representing phase morphology in the Takayanagi model, whereas the product λφ is the volume fraction of the dispersed phase, and is related to the degree of series parallel coupling.Parameters λ and φ vary with composition and with the change in the state of dispersion.For spherical particles independently and homogeneously dispersed in a matrix, it can be assumed that λ is equal to φ. 27,28 The Figure 2 showed that calculated models have higher values than measured experimental values for iPP/ m-EPR blends.Both Takayanagi's models showed almost the same behavior as classic series and parallel model in this case.[27][28]

2. 2. Yield stress and Strain (Tensile Strength and Elongation at Yield)
Yield stress gives additional information on polymer matrix-elastomer interactions in binary blends besides how the elastomers affect yield stress as impact modifiers. 2,3Steady, monotonous decrease of σ y values with addition of both, m-EPR1 and m-EPR2 elastomers (Figure 3) indicates gradually increase of toughening similarly to gradually reduced stiffness (Figure 2) with increased elastomer content.Slightly higher σ y values of the iPP/m-EPR2 than iPP/m-EPR1 blends at higher elastomer contents might be ascribed to different factors and will be discussed at Tensile strength and elongation at break section.
EPR blends containing spherical particles of m-EPR with proved good adhesion, and exhibits somewhat lower values comparing to experimental values (Figure 3). 30he extent of yield strain, ε y , of neat semicrystalline iPP primarily depends on the strengthening of tie molecules in amorphous interlayer (intercrystalline links) and interspherulitic links.Whereas the addition of m-EPR1 affects the elongation at yield negligibly, the addition of m-EPR2 increases yield strain steadily (Figure 4).Stronger strengthening effect of m-EPR2 than m-EPR1 elastomer has been also observed at ternary iPP/silica/m-EPR and composites. 31It could be ascribed to better stress transfer from softer m-EPR2 particles as bumpers and better miscibility of m-EPR2 than m-EPR1 with iPP matrix, and might also lead to higher elongations with regard to stiffer m-EPR1 particles.However, more significant divergence in strain behavior in present case could be reasonable due to more effective stretching in simpler binary blend system (without filler).Nicolais and Narkis developed a model for yield strength of polymeric materials containing spherical particles for class of polymer systems based on the interphase properties. 29According to Nicolais-Narkis model, when interfacial adhesion does not exist between polymer and elastomer, the particles in matrix cannot bear the stress and it could be carried only through the matrix.Nevertheless, when a good interfacial adhesion is provided between matrix and dispersed phase the interfacial layer can transfer a fraction of stress from matrix to dispersed phase.So in this case the yield strength includes both matrix and dispersed phase contributions so the simplified equation can be expressed: (9)   where σ b and σ m are yield strength of blend and matrix and Φ f is the volume fraction of particles, assuming that dispersed particles in polymer matrix are spherical and there is a good adhesion.This model corresponds well to iPP/m-

2. Tensile Strength and Elongation at Break
Although the incorporation of elastomeric modifiers into iPP matrix might have complex influence to the tensile strength at break, σ b values of the iPP/m-EPR blends monotonously decrease with increased elastomer content (Figure 5) similarly to steady decrease of E (Figure 2) and σ y (Figure 3) values.Somewhat higher σ y and σ b values of the iPP/m-EPR2 than for iPP/m-EPR1 blends at higher m-EPR2 contents, has been primarily conducted (driven) by the difference in molecular weights of elastomers analogous to similar yield stress behavior.
Higher values of iPP/m-EPR2 might also be ascribed to higher crystallinity and spherulite size, compatibility or miscibility of the iPP/m-EPR2 than iPP/m-EPR1 blends and to stronger interfacial effect (interfacial free energy ) at iPP-m-EPR2 interface.However, the effects of mentioned factors could not be resolved and ascribed to any of mentioned influencing factors due to slight difference in σ y and σ b values between these two m-EPR elastomers.
Higher viscosity iPP/m-EPR2 ratio than iPP/m-EPR1 (Figure 1) leads to smaller size of dispersed m-EPR2 than m-EPR1 particles. 31Moreover, prolonged crystallization of iPP matrix with additions of both m-EPR's was affected by migration of iPP chains from the remained melt islands of both elastomers, i.e. by solidification effect. 31owever, higher partial miscibility of the iPP with m-EPR2 than m-EPR1 (proved exactly by DMA 31 ) as well as m-EPR2 with lower molecular mass and higher mobility of macromolecules than m-EPR1 macromolecules may more easily diffuse into the iPP interlamellar amorphous layer where they may form domains more or less interconnected with the amorphous iPP phase, thus increasing its thickness. 16his statement was proved by higher spherulite size of blends with m-EPR2 than m-EPR1 elastomer. 31Intraspherulitically accommodated smaller m-EPR's dispersed particles beside their interspherulitically accommodation may indicate better stress transfer from softer m-EPR2 particles as bumpers and might also lead to higher elongations additionally.
in large concentration range.The slopes of ε b iPP/m-EPR for both added elastomers are very similar because of very similar structure of both elastomers.

Impact Properties
The incorporation of the m-EPR elastomers toughness plastomeric iPP matrix and increases impact strength, a K , values almost exponentially (Figure 7).The both m-EPR's considerably improve a K at additions higher than 10 vol.% of m-EPR's analogously to similar behavior with addition of poly(styrene-b-ethylene-co-propylene) in iPP. 28hese results proved that both m-EPR's have efficient rubber-toughening characteristics for polypropylene.It is known that the phase separation is essential for producing impact-resistant blends for many polymeric systems.The m-EPR elastomer dissolved in the matrix phase can act as a plasticizer, reducing the glass-transition temperature and stiffness of the matrix without increasing its toughness. 32owever, other important facts influencing the impact strength of the iPP must be considered in addition to the afore mentioned facts: (non)existence of β-phase iPP, stiffness reduction, particle-matrix adhesion (or miscibility), etc.The iPP/m-EPR's blends exhibited mainly monoclinic α-form of the iPP in iPP/m-EPR blends, 33 in distinct to the appearing of β-phase in iPP/SEP blends with poly(styrene-b-ethylene-co-propylene), 28 with superior impact resistance to α-phase iPP in present iPP/m-EPR blends. 34owever, the toughness of the iPP/m-EPR blends is commensurable with the iPP/SEP blends. 28This fact indicates that new metallocene m-EPR copolymers exhibit higher toughening effect in comparison to SEP elastomer as custom SBC copolymer toughening agents. 28Altough the iP-P/m-EPR2 blend exhibited doubtless higher degree of miscibility than iPP/m-EPR1 blends, 33 higher a K values of the iPP/m-EPR1 than for iPP/m-EPR2 blend could be observed in whole concentration range (Figure 7).This fact The reason for such profound increase is probably the plasticization effect caused by addition of the m-EPR elastomer that has great impact on elongation properties of blends acting like plasticizers dissolved in the matrix phase could be explained by almost twice higher molecular weight of m-EPR1 than m-EPR2, e.g. by MFI value of m-EPR1 commensurable with the iPP (Table 1) that might affect impact strength in two ways.First, dispersed particles of copolymer with longer macromolecules exhibit higher toughness.Secondly, longer macromolecules or longer olefins segments similar to this one of the iPP chains may provide stronger mutual entanglements improving thus the notched impact strength (Figure 7).Similar difference in toughening effects of these two m-EPR's copolymers has been observed in composites of the iPP/ wollastonite and iPP/silica. 31,35bviously, the effect of macromolecular length prevails the effect of miscibility in toughening of iPP/m-EPR blends.
axes.This assumes a tensile yield stress of matrix (σ yp ) to be constant.
Calculated lnσ rel values were presented in Figure 8 in dependence on elastomer content and proportional to values of Pukanszky's 36 interaction parameter showed in Table 3. Higher interaction parameter B value for iPP/m-EPR2 (1.13) than for iPP/m-EPR1 blend (0.82) corresponds to higher σ y values for iPP/m-EPR2 blend.This fact corresponds well with proved higher miscibility of iPP/m-EPR2 than iPP/m-EPR1 blends. 33

4. 1. Adhesion Parameters of iPP/m-EPR Blends
Interfacial properties may also affect the strength of polymer-elastomer interactions.The results of the studies on the effective adhesion for a given system indicate some conditions as optimal: thermodynamic work of adhesion as a maximal, spreading coefficient as a positive value and interfacial free energy as a minimal (tends to null) (Table 3). 21,37,38The surface free energy of the polypropylene and elastomers are showed in Table 4.

4. 1. Parameter Interactivity B of iPP/m-EPR Blends
The strength of polymer-elastomer interactions can be quantitatively described using Pukanszky's model for particle-based composites, as described in equation (10). 36ore specifically, equation (10) allows to investigate a linear relationship existing between the natural logarithm: (10)   where σ yc is the yield stress of elastomer and σ yp is the yield stresses of matrix, respectively; B is a term corresponding to the load carrying capability of the elastomer and depends on elastomer-matrix interactions; φ d is the elastomer volumetric fraction within polymer matrix.If ln[σ yc (1 + 2.5Φ f )/(σ yp (1 -Φ f )] of fraction value is plotted against of elastomer, parameter B can be calculated as a line slope, with intercept in cross section of coordinate parameter   4).The surface free energy for m-EPR1 elastomer is close to value for iPP.The ethylene-propylene copolymers m-EPR1 and m-EPR2 differed in polar component of surface free energy and the m-EPR1 is more polar than m-EPR2 and iPP with almost similar polarity.
Interfacial free energy, γ AB , work of adhesion, W AB , and spreading coefficient, S AB , of all polymer/elastomer pairs for the iPP/m-EPR blends were calculated according to equations (2-4) (Table 5).
However, higher interfacial free energy for iPP-m-EPR1 (γ = 2.32 mJ/m 2 ) than for iPP-m-EPR2 (γ = 0.78 mJ/ m 2 ) indicates contrary -stronger interfacial effect of the iPP-m-EPR2 than for iPP-m-EPR1 interface.In this case the interfacial free energy, as the inversely proportioned to the strength of intermolecular interactions in polymer blends, would be more relevant for such ambiguous systems. 39,40,41Higher interaction parameter B value for the iPP/m-EPR2 than for iPP/m-EPR1 blend seemed to confirm this ambiguous fact.

5. Miscibility/Compatibility and Interactivity
Better miscibility of the iPP/m-EPR2 than iPP/m-EPR1 blend was confirmed with Dinamic Mechanical Analysis, DMA (one mutual intermediary maximum in E''/T curve of the iPP/m-EPR2 blend comparison to two overlapped β-relaxation maxima of the iPP/m-EPR1 blend) in our previous paper. 33The DMA results as well as biphasic morphology observed by all microscopy techniques suggests that m-EPR2 molecules are not completely dissolved into the iPP amorphous region, i.e. partial miscibility and compatibility between m-EPR2 particles and iPP matrix is better than with m-EPR1. 33The higher crystallinity due to crystallization across phase boundary at dispersed m-EPR2 particles and increased spherulite size in the iPP/m-EPR2 may affect the yield stress of semicrystalline polymers besides higher miscibility/ compatibility. 42,43he effect of spherulite size on yield stress depends on its position on summary curve tensile strength as a function of spherulite size related to the intraspherulite yield. 31Intraspherulitical location of both dispersed m-EPR particles in the iPP matrix had been observed by polarized optical micrographs 31    The difference is only in somewhat thinner dispersed m-EPR2 (up to 1,2 μm) than m-EPR1 particles (up to 2.5 μm) due to Jordhamo law. 44It is well known that dispersed particle size and distribution may affect yield properties.It was proved that the particle size of the elastomer significantly affects the deformation and failure processes in polypropylene toughened with olefinic elastomer being small particle favouring shear yielding while coarser dispersion promotes crazing due to difference in an average surface-to-surface interparticle distance. 45,46,47

6. Optimization Diagrams of Mechanical Properties of iPP/m-EPR Blends
Mechanical properties are one of the most respected criteria for choosing right materials for some end-use pur-Švab et al.: Polypropylene Blends with m-EPR Copolymers: ... pose.Schematic diagrams show the change in some important materials' mechanical properties by introducing one or two components in polymer matrix.The optimization diagrams of such designed materials were used for comparing their mechanical parameters with the pure isotactic polypropylene.
The addition of propylene-ethylene elastomers in isotactic polypropylene decreased the Young's modulus as expected due to toughening effect of elastomers.The yield strength and strength at break also decrease by addition of elastomers and the values are higher for the blends with m-EPR2 elastomer with smaller molecular mass.The few times bigger increase in impact strength in comparison to iPP is the result of addition of soft elastomers in large concentration so the role of impact modifier is completely fulfilled.Higher a K values of the iPP/m-EPR1 than for iPP/ m-EPR2 blend could be explained by almost twice higher molecular weight (longer macromolecules) of m-EPR1 than m-EPR2.Optimization diagram (Figure 10) indicate good balancing of mechanical properties besides efficient effect of metallocene m-EPR copolymers as impact modifiers for polypropylene.
well as torque values of the iPP/m-EPR1 blends were higher of the iPP/m-EPR2 blends due to higher molecular mass, e.g. higher molten viscosity of m-EPR1 than m-EPR2 copolymer.However, slight divergence of almost linearly decreased E, σ y and σ b values of the iPP/m-EPR's blends could be ascribed to different factors (difference in crystallinity and spherulite size, compatibility or miscibility of the iPP with m-EPR's, and interfacial effect at iPP-m-EPR interface) which could not be resolved.So the behavior of these values could not be ascribed to any of mentioned influencing factors particularly; it could be only concluded that the difference in viscosity or molecular length between two m-EPR's does not affect E, σ y and σ b values.Somewhat divergence of yield strain values resembles to similar divergence of torque values but in inverse mode.Whereas this divergence in torque values was governed by difference in molten viscosity of copolymers, the divergence of ε y values was governed by difference in miscibility of m-EPR's with iPP matrix and by difference in stress transfer from m-EPR particles differently soft.Moreover, optimization diagrams indicated beside efficient effect of metallocene m-EPR copolymers as impact modifiers for polypropylene also its balancing effect of mechanical properties.

Conclusions
The effects of two metallocene ethylene-propylene-based elastomers with varied contents (2,5-20 vol.% of m-EPR1 and m-EPR2) differing in molecular mass (viscosity) on mechanical, rheological and interfacial properties of the iPP/m-EPR blends were investigated.While Young's modulus, tensile strength and yield and break of the iPP/m-EPR's blends decreased, impact strength and elongation at break increased with increased elastomer content.Such behavior of presented iPP/m-EPR blends resulted primarily by prevailed toughening or plastification effect caused by spherically shaped dispersed m-EPR particles.Thereby, elongation at break and impact strength as

Figure 1 .Figure 2 .
Figure 1.Steady state torque of the iPP/m-EPR blends in dependance on volume content of added elastomers

Figure 3 .
Figure 3. Tensile strength at yield of the iPP/m-EPR blends in dependence on volume content of added elastomers and Nicolais-Narkis model for yield strength

Figure 4 .
Figure 4. Elongation at yield of the iPP/m-EPR blends in dependence on volume content of added elastomers

Figure 5 .
Figure 5. Tensile strength at break of the iPP/m-EPR blends in dependence on volume content of added elastomers

Figure 6 .
Figure 6.Elongation at break of the iPP/m-EPR blends in dependence on volume content of added elastomer

Figure 7 .
Figure 7. Notched impact strength of the iPP/m-EPR blends in dependence on volume content of added elastomers

Figure 10 .
Figure 10.Optimization diagram of mechanical properties of iPP/ m-EPR blends with 20 vol.% of added elastomers

Table 1 .
The properties of used materials

Table 2 .
Surface free energy (γ), dispersion (γ d ) and polar components (γ p ) of surface free energy of test liquids used for contact angle measurements

Table 4 .
21e surface free energy (γ) of the iPP and elastomers and their dispersive (γ d ) and polar component values (γ p ) evaluated by using the Wu's model21 Švab et al.: Polypropylene Blends with m-EPR Copolymers: ...

Table 5 .
Adhesion parameters γ AB , W AB , S AB of the iPP/m-EPR blends *γ mf for calculation according to Wu's equation